Publicación: Coagulation-flocculation sequential with Fenton or Photo-Fenton processes as an alternative for the industrial textile wastewater treatment
Fecha
2017-04-15
Autores
GilPavas, E.
Dobrosz-Gómez, I.
Gómez-García, M.Á.
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Resumen
In this study, the industrial textile wastewater was treated using a chemical-based technique (coagulation-flocculation, C-F) sequential with an advanced oxidation process (AOP: Fenton or Photo-Fenton). During the C-F, Al2(SO4)3 was used as coagulant and its optimal dose was determined using the jar test. The following operational conditions of C-F, maximizing the organic matter removal, were determined: 700 mg/L of Al2(SO4)3 at pH = 9.96. Thus, the C-F allowed to remove 98% of turbidity, 48% of Chemical Oxygen Demand (COD), and let to increase in the BOD5/COD ratio from 0.137 to 0.212. Subsequently, the C-F effluent was treated using each of AOPs. Their performances were optimized by the Response Surface Methodology (RSM) coupled with a Box-Behnken experimental design (BBD). The following optimal conditions of both Fenton (Fe2+/H2O2) and Photo-Fenton (Fe2+/H2O2/UV) processes were found: Fe2+ concentration = 1 mM, H2O2 dose = 2 mL/L (19.6 mM), and pH = 3. The combination of C-F pre-treatment with the Fenton reagent, at optimized conditions, let to remove 74% of COD during 90 min of the process. The C-F sequential with Photo-Fenton process let to reach 87% of COD removal, in the same time. Moreover, the BOD5/COD ratio increased from 0.212 to 0.68 and from 0.212 to 0.74 using Fenton and Photo-Fenton processes, respectively. Thus, the enhancement of biodegradability with the physico-chemical treatment was proved. The depletion of H2O2 was monitored during kinetic study. Strategies for improving the reaction efficiency, based on the H2O2 evolution, were also tested. © 2017 Elsevier Ltd
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aluminum sulfate , ferrous gluconate , hydrogen peroxide , organic matter , hydrogen peroxide , industrial waste , iron , waste water , water pollutant , biodegradation , chemical oxygen demand , coagulation , dose-response relationship , experimental design , flocculation , industrial waste , numerical method , organic matter , oxidation , physicochemical property , pollutant removal , wastewater treatment , analysis of variance , Article , biochemical oxygen demand , biodegradability , chemical oxygen demand , controlled study , effluent , experimental design , flocculation , oxidation , pH , response surface method , textile industry , turbidity , waste water management , flocculation , industrial waste , oxidation reduction reaction , sewage , textile , waste water , water pollutant , Flocculation , Hydrogen Peroxide , Industrial Waste , Iron , Oxidation-Reduction , Textiles , Waste Disposal , Fluid , Waste Water , Water Pollutants , Chemical