Examinando por Materia "calibration"
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Ítem Quantitative biostratigraphic model for the tertiary of the lower Magdalena Basin, Colombian Caribbean(Ecopetrol, 2006-01-01) Cuartas, C.; Jaramillo, C.; Martínez, J.-I.; Universidad EAFIT. Departamento de Geología; Ciencias del MarThe reinterpretation of biostratigraphic information by new models and quantitative correlation techniques substantially improves its resolution and its correlative potential, thus minimizing oil exploration risks. With this aim, biostratigraphic information, i.e. first (FO) and last (LO) occurrence events of benthonic and planktonic foraminifera was analysed from sixteen wells from the Lower Magdalena Valley (LMV). The inconsistencies found in the biostratigraphic record, i.e. varying successions of first and last appearances of species from well to well as a result of several factors such incomplete sampling and preservation, true variation in the distribution of fosil taxa, etc., and the great amount of biostratigraphic data makes it practically impossible to accurately constrain basin history from biostratigraphic information by unaided visual inspection. This motivates the treatment of biostratigraphic information with new quantitative approaches, such as constrained optimization (CONOP9 software) and graphic correlation concepts (GraphCor 3,0) and the comparative method approach of Cooper et al. (2001). The succession of biostratigraphic events found through the application of each technique was statistically filtered and compared with Kendall tau coefficients whose values were 0,8. An optimal biostratigraphic succession of LOs was found and calibrated with the Berggren et al. (1995) global time scale by a LOESS regression model for the middle Eocene-Pliocene interval, thus revealing three major changes in sediment accumulation rates for the basin during this time interval: (1) middle Eocene to Oligocene, with low accumulation rates, (2) early Miocene to middle Miocene, with high accumulation rates and (3) late Miocene to Pliocene, with lower accumulation rates. The calibrated composite succession enabled the construction of age-well depth plots, which indicate periods of local deposition and accumulation rates, and periods of erosion, no deposition or very low accumulation rates (unconformities). The best plots were used to build a model for the correlation of unconformities, which shows that they are heterochronous, lasted at least 2,5 Ma, and are of limited extent. Finally, a correlation model was proposed that includes: (1) a time-calibrated succession of biostratigraphic events, and (2) a Haq curve that shows how each geologic period is recorded in each well.Ítem Simultaneous Fluorometric Determination of Chlorophylls a and b and Pheophytins a and b in Olive Oil by Partial Least-Squares Calibration(AMER CHEMICAL SOC, 2003-11-19) Diaz, TG; Meras, ID; Correa, CA; Roldan, B; Caceres, MIR; Diaz, TG; Meras, ID; Correa, CA; Roldan, B; Caceres, MIR; Universidad EAFIT. Departamento de Ingeniería de Producción; Ingeniería, Energía, Exergía y Sostenibilidad (IEXS)The resolution of quaternary mixtures of chlorophylls a and b and pheophytins a and b has been accomplished by partial least-squares (PLS) multivariate calibration, applied to the fluorescence signals of these pigments. The total luminescence information of the compounds has been used to optimize the spectral data set to perform the calibration. After preliminary studies, a method is described in acetone media, to avoid emulsions with the olive oil samples. Different scanning paths have been selected for each method. For the simultaneous determination of the pigments in olive oil samples, a comparative study of the results found by using excitation, emission, and synchronous spectral data, as analytical signal, was performed. The excitation spectra were selected as the better analytical signals for the determination of the pigments in olive oil samples. The optimum wavelength range to record the excitation spectra (?em = 662 nm) was selected to minimize the contribution of pheophytin a and to maximize the contribution of the other pigments, which are the minor constituents in olive oil. Determination of these pigments in olive oil samples was effected from the excitation spectra of dissolutions o suitable aliquots in acetone. Recovery values from olive oil, spiked with chlorophylls a and b and pheophytins a and b, were in the ranges of 70-112, 71-111, 76-105, and 82-109%, respectively.Ítem Southwest Pacific Ocean response to a warmer world: Insights from marine isotope stage 5e(AMER GEOPHYSICAL UNION, 2013-09-01) Cortese, G.; Dunbar, G. B.; Carter, L.; Scott, G.; Bostock, H.; Bowen, M.; Crundwell, M.; Hayward, B. W.; Howard, W.; Martinez, J. I.; Moy, A.; Neil, H.; Sabaa, A.; Sturm, A.; Universidad EAFIT. Departamento de Geología; Ciencias del MarPaleoceanographic archives derived from 17 marine sediment cores reconstruct the response of the Southwest Pacific Ocean to the peak interglacial, Marine Isotope Stage (MIS) 5e (ca. 125 ka). Paleo-Sea Surface Temperature (SST) estimates were obtained from the Random Forest model - an ensemble decision tree tool - applied to core-top planktonic foraminiferal faunas calibrated to modern SSTs. The reconstructed geographic pattern of the SST anomaly (maximum SST between 120 and 132 ka minus mean modern SST) seems to indicate how MIS 5e conditions were generally warmer in the Southwest Pacific, especially in the western Tasman Sea where a strengthened East Australian Current (EAC) likely extended subtropical influence to ca. 45°S off Tasmania. In contrast, the eastern Tasman Sea may have had a modest cooling except around 45°S. The observed pattern resembles that developing under the present warming trend in the region. An increase in wind stress curl over the modern South Pacific is hypothesized to have spun-up the South Pacific Subtropical Gyre, with concurrent increase in subtropical flow in the western boundary currents that include the EAC. However, warmer temperatures along the Subtropical Front and Campbell Plateau to the south suggest that the relative influence of the boundary inflows to eastern New Zealand may have differed in MIS 5e, and these currents may have followed different paths compared to today. Key Points Oceanic conditions at 125 kyr seem to agree with recent observations/trendsEast Australian Current probably stronger and Tasman Front cooler during MIS 5eObserved oceanographic changes likely linked to increases in wind stress curl ©2013. American Geophysical Union. All Rights Reserved.