Using scrap zero valent iron to replace dissolved iron in the Fenton process for textile wastewater treatment: Optimization and assessment of toxicity and biodegradability

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dc.citation.journalTitleENVIRONMENTAL POLLUTIONeng
dc.contributor.authorGilPavas, Edison
dc.contributor.authorCorrea-Sanchez, Santiago
dc.contributor.authorAcosta, Diego A.
dc.contributor.departmentUniversidad EAFIT. Departamento de Ingeniería de Procesosspa
dc.contributor.researchgroupDesarrollo y Diseño de Procesosspa
dc.date.accessioned2021-04-12T19:06:22Z
dc.date.available2021-04-12T19:06:22Z
dc.date.issued2019-09-01
dc.description.abstractA Fenton like advanced oxidation process (AOP) employing scrap zerovalent iron (SZVI) and hydrogen peroxide (H2O2) was studied for industrial textile wastewater treatment from a textile manufacturing plant located at Medellin, Colombia (South America). The wastewater effluent studied contains a mixture of organic compounds resistant to conventional treatments. The effect of initial pH and SZVI concentration and H2O2 concentration were studied by a response surface methodology (RSM) Box-Behnken design of experiment (BBD). The combined SZVI/H2O2 process led to reductions of 95% color, 76% of chemical oxygen demand (COD) and 71% of total organic carbon (TOC) at optimal operating conditions of pH = 3, SZVI = 2000 mg/L and [H2O2] = 24.5 mM. Molecular weight distribution measurement (MWD), ultraviolet-visible (UV-Vis) spectroscopy, HPLC, biodegradability and toxicity were used to characterize the pollutants after the treatment process finding that the resulting effluent was polluted mostly by low molecular weight carboxylic acids. A remarkable biodegradability enhancement of the effluent was evidenced by a BOD5/COD ratio increase from 0.22 to 0.4; also, the SZVI/H2O2 process successfully reduced the toxicity from 60% to 20% of dead A. Salina crustaceans. (C) 2019 Elsevier Ltd. All rights reserved.eng
dc.identifierhttps://eafit.fundanetsuite.com/Publicaciones/ProdCientif/PublicacionFrw.aspx?id=10268
dc.identifier.doi10.1016/j.envpol.2019.06.104
dc.identifier.issn02697491
dc.identifier.issn18736424
dc.identifier.otherWOS;000483405400082
dc.identifier.otherPUBMED;31284213
dc.identifier.otherSCOPUS;2-s2.0-85068409534
dc.identifier.urihttp://hdl.handle.net/10784/28272
dc.language.isoeng
dc.publisherElsevier Ltd.
dc.relationDOI;10.1016/j.envpol.2019.06.104
dc.relationWOS;000483405400082
dc.relationPUBMED;31284213
dc.relationSCOPUS;2-s2.0-85068409534
dc.relation.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85068409534&doi=10.1016%2fj.envpol.2019.06.104&partnerID=40&md5=f9b0b6765f8751826edcca0b1ed8877f
dc.rightshttps://v2.sherpa.ac.uk/id/publication/issn/0269-7491
dc.sourceENVIRONMENTAL POLLUTION
dc.subjectIndustrial textile wastewatereng
dc.subjectAdvanced treatmenteng
dc.subjectScrap zerovalent iron (SZVI)eng
dc.subjectH2O2eng
dc.subjectOptimizationeng
dc.subjectToxicityeng
dc.titleUsing scrap zero valent iron to replace dissolved iron in the Fenton process for textile wastewater treatment: Optimization and assessment of toxicity and biodegradabilityeng
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion
dc.typeinfo:eu-repo/semantics/articleeng
dc.typearticleeng
dc.typeinfo:eu-repo/semantics/publishedVersioneng
dc.typepublishedVersioneng
dc.type.localArtículospa

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