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Ítem Efficient treatment for textile wastewater through sequential electrocoagulation, electrochemical oxidation and adsorption processes: Optimization and toxicity assessment(Elsevier BV, 2020-01-01) GilPavas E.; Dobrosz-Gómez I.; Gómez-García M.-Á.; GilPavas E.; Dobrosz-Gómez I.; Gómez-García M.-Á.; Universidad EAFIT. Departamento de Ingeniería de Procesos; Procesos Ambientales (GIPAB)In this work, the sequential Electrocoagulation + Electro-oxidation + Activated carbon adsorption (EC + EO + AC) process was studied as an alternative for the treatment of an industrial textile wastewater (TWW) issuing from a manufacturing company located in Medellín (Colombia). The EC's and EO's operational conditions were optimized using a Box-Behnken experimental design, the Response Surface Methodology and a constrained nonlinear optimization algorithm in terms of organic matter degradation efficiency. The best performance for EC (i. e., dye removal = 94%, COD and TOC degradation of 45 and 40%, respectively) was obtained using Fe anode and Boron Doped Diamond (BDD) cathode, with current density, jEC, equals to 5 mA/cm2, pH = 9.3, 60 RPM and 10 min of electrolysis. After EC treatment, the effluent biodegradability (evaluated as the BOD5/COD ratio) increases from 0.14 to 0.23. Regrettably, EC was not effective for the removal of acute toxicity to Artemia salina since the treated effluent remained very toxic (100%). The treatment of EC's effluent by EO enhanced organic pollutant removal. For EC + EO sequential process, EO optimal operational conditions (jEO = 10 mA/cm2, pH = 3, 240 RPM, BDD as anode and Fe as cathode) allowed reduction of 100% of color, 88% of COD and 79% of TOC after 30 min of electrolysis. Moreover, the BOD5/COD ratio increased from 0.23 to 0.58; however, the treated effluent remained very toxic to the Artemia salina. Consequently, an activated carbon adsorption step was included to complete the treatment process. Thus, by coupling the EC + EO + AC process, effluent's acute toxicity decreased completely. From molecular weight distribution analysis, it was concluded that EC + EO was efficient in eliminating low molecular weight (< 5 kDa) compounds. Finally, the operation cost, which includes chemical reagents, electrodes, energy consumption, and sludge disposal, for the EC + EO + AC sequential process was estimated in 3.83 USD /m3. © 2020 Elsevier B.V.Ítem Efficient treatment for textile wastewater through sequential electrocoagulation, electrochemical oxidation and adsorption processes: Optimization and toxicity assessment(Elsevier BV, 2020-01-01) GilPavas E.; Dobrosz-Gómez I.; Gómez-García M.-Á.; Universidad EAFIT. Departamento de Ingeniería de Procesos; Desarrollo y Diseño de ProcesosIn this work, the sequential Electrocoagulation + Electro-oxidation + Activated carbon adsorption (EC + EO + AC) process was studied as an alternative for the treatment of an industrial textile wastewater (TWW) issuing from a manufacturing company located in Medellín (Colombia). The EC's and EO's operational conditions were optimized using a Box-Behnken experimental design, the Response Surface Methodology and a constrained nonlinear optimization algorithm in terms of organic matter degradation efficiency. The best performance for EC (i. e., dye removal = 94%, COD and TOC degradation of 45 and 40%, respectively) was obtained using Fe anode and Boron Doped Diamond (BDD) cathode, with current density, jEC, equals to 5 mA/cm2, pH = 9.3, 60 RPM and 10 min of electrolysis. After EC treatment, the effluent biodegradability (evaluated as the BOD5/COD ratio) increases from 0.14 to 0.23. Regrettably, EC was not effective for the removal of acute toxicity to Artemia salina since the treated effluent remained very toxic (100%). The treatment of EC's effluent by EO enhanced organic pollutant removal. For EC + EO sequential process, EO optimal operational conditions (jEO = 10 mA/cm2, pH = 3, 240 RPM, BDD as anode and Fe as cathode) allowed reduction of 100% of color, 88% of COD and 79% of TOC after 30 min of electrolysis. Moreover, the BOD5/COD ratio increased from 0.23 to 0.58; however, the treated effluent remained very toxic to the Artemia salina. Consequently, an activated carbon adsorption step was included to complete the treatment process. Thus, by coupling the EC + EO + AC process, effluent's acute toxicity decreased completely. From molecular weight distribution analysis, it was concluded that EC + EO was efficient in eliminating low molecular weight (< 5 kDa) compounds. Finally, the operation cost, which includes chemical reagents, electrodes, energy consumption, and sludge disposal, for the EC + EO + AC sequential process was estimated in 3.83 USD /m3. © 2020 Elsevier B.V.Ítem Temperature regulation of a pilot-scale batch reaction system via explicit model predictive control(Universidad EAFIT, 2015) Sánchez-Cossio, Javier; Ortega-Álvarez, Juan David; Ocampo-Martínez, CarlosIn this paper, the temperature of a pilot-scale batch reaction system is modeled towards the design of a controller based on the explicit model predictive control (EMPC) strategy -- Some mathematical models are developed from experimental data to describe the system behavior -- The simplest, yet reliable, model obtained is a (1,1,1)-order ARX polynomial model for which the mentioned EMPC controller has been designed -- The resultant controller has a reduced mathematical complexity and, according to the successful results obtained in simulations, will be used directly on the real control system in a next stage of the entire experimental frameworkÍtem Weighted area/angle distortion minimization for Mesh Parameterization(EMERALD GROUP PUBLISHING LIMITED, 2017-01-01) Mejia D.; Acosta D.A.; Ruiz-Salguero O.; Universidad EAFIT. Departamento de Ingeniería de Procesos; Desarrollo y Diseño de ProcesosPurpose: Mesh Parameterization is central to reverse engineering, tool path planning, etc. This work synthesizes parameterizations with un-constrained borders, overall minimum angle plus area distortion. This study aims to present an assessment of the sensitivity of the minimized distortion with respect to weighed area and angle distortions. Design/methodology/approach: A Mesh Parameterization which does not constrain borders is implemented by performing: isometry maps for each triangle to the plane Z = 0; an affine transform within the plane Z = 0 to glue the triangles back together; and a Levenberg-Marquardt minimization algorithm of a nonlinear F penalty function that modifies the parameters of the first two transformations to discourage triangle flips, angle or area distortions. F is a convex weighed combination of area distortion (weight: a with 0 = a = 1) and angle distortion (weight: 1 - a). Findings: The present study parameterization algorithm has linear complexity [O(n), n = number of mesh vertices]. The sensitivity analysis permits a fine-tuning of the weight parameter which achieves overall bijective parameterizations in the studied cases. No theoretical guarantee is given in this manuscript for the bijectivity. This algorithm has equal or superior performance compared with the ABF, LSCM and ARAP algorithms for the Ball, Cow and Gargoyle data sets. Additional correct results of this algorithm alone are presented for the Foot, Fandisk and Sliced-Glove data sets. Originality/value: The devised free boundary nonlinear Mesh Parameterization method does not require a valid initial parameterization and produces locally bijective parameterizations in all of our tests. A formal sensitivity analysis shows that the resulting parameterization is more stable, i.e. the UV mapping changes very little when the algorithm tries to preserve angles than when it tries to preserve areas. The algorithm presented in this study belongs to the class that parameterizes meshes with holes. This study presents the results of a complexity analysis comparing the present study algorithm with 12 competing ones. © Emerald Publishing Limited.Ítem Weighted area/angle distortion minimization for Mesh Parameterization(EMERALD GROUP PUBLISHING LIMITED, 2017-01-01) Mejia D.; Acosta D.A.; Ruiz-Salguero O.; Universidad EAFIT. Departamento de Ingeniería Mecánica; Laboratorio CAD/CAM/CAEPurpose: Mesh Parameterization is central to reverse engineering, tool path planning, etc. This work synthesizes parameterizations with un-constrained borders, overall minimum angle plus area distortion. This study aims to present an assessment of the sensitivity of the minimized distortion with respect to weighed area and angle distortions. Design/methodology/approach: A Mesh Parameterization which does not constrain borders is implemented by performing: isometry maps for each triangle to the plane Z = 0; an affine transform within the plane Z = 0 to glue the triangles back together; and a Levenberg-Marquardt minimization algorithm of a nonlinear F penalty function that modifies the parameters of the first two transformations to discourage triangle flips, angle or area distortions. F is a convex weighed combination of area distortion (weight: a with 0 = a = 1) and angle distortion (weight: 1 - a). Findings: The present study parameterization algorithm has linear complexity [O(n), n = number of mesh vertices]. The sensitivity analysis permits a fine-tuning of the weight parameter which achieves overall bijective parameterizations in the studied cases. No theoretical guarantee is given in this manuscript for the bijectivity. This algorithm has equal or superior performance compared with the ABF, LSCM and ARAP algorithms for the Ball, Cow and Gargoyle data sets. Additional correct results of this algorithm alone are presented for the Foot, Fandisk and Sliced-Glove data sets. Originality/value: The devised free boundary nonlinear Mesh Parameterization method does not require a valid initial parameterization and produces locally bijective parameterizations in all of our tests. A formal sensitivity analysis shows that the resulting parameterization is more stable, i.e. the UV mapping changes very little when the algorithm tries to preserve angles than when it tries to preserve areas. The algorithm presented in this study belongs to the class that parameterizes meshes with holes. This study presents the results of a complexity analysis comparing the present study algorithm with 12 competing ones. © Emerald Publishing Limited.Ítem Weighted area/angle distortion minimization for Mesh Parameterization(EMERALD GROUP PUBLISHING LIMITED, 2017-01-01) Mejia D.; Acosta D.A.; Ruiz-Salguero O.; Mejia D.; Acosta D.A.; Ruiz-Salguero O.; Universidad EAFIT. Departamento de Ingeniería de Procesos; Procesos Ambientales (GIPAB)Purpose: Mesh Parameterization is central to reverse engineering, tool path planning, etc. This work synthesizes parameterizations with un-constrained borders, overall minimum angle plus area distortion. This study aims to present an assessment of the sensitivity of the minimized distortion with respect to weighed area and angle distortions. Design/methodology/approach: A Mesh Parameterization which does not constrain borders is implemented by performing: isometry maps for each triangle to the plane Z = 0; an affine transform within the plane Z = 0 to glue the triangles back together; and a Levenberg-Marquardt minimization algorithm of a nonlinear F penalty function that modifies the parameters of the first two transformations to discourage triangle flips, angle or area distortions. F is a convex weighed combination of area distortion (weight: a with 0 = a = 1) and angle distortion (weight: 1 - a). Findings: The present study parameterization algorithm has linear complexity [O(n), n = number of mesh vertices]. The sensitivity analysis permits a fine-tuning of the weight parameter which achieves overall bijective parameterizations in the studied cases. No theoretical guarantee is given in this manuscript for the bijectivity. This algorithm has equal or superior performance compared with the ABF, LSCM and ARAP algorithms for the Ball, Cow and Gargoyle data sets. Additional correct results of this algorithm alone are presented for the Foot, Fandisk and Sliced-Glove data sets. Originality/value: The devised free boundary nonlinear Mesh Parameterization method does not require a valid initial parameterization and produces locally bijective parameterizations in all of our tests. A formal sensitivity analysis shows that the resulting parameterization is more stable, i.e. the UV mapping changes very little when the algorithm tries to preserve angles than when it tries to preserve areas. The algorithm presented in this study belongs to the class that parameterizes meshes with holes. This study presents the results of a complexity analysis comparing the present study algorithm with 12 competing ones. © Emerald Publishing Limited.