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Ítem First and second thermodynamic law analyses applied to spark ignition engines modelling and emissions prediction(Springer-Verlag France, 2016-11-01) Duque Amaya, A.F.; Díaz Torres, A.G.; Acosta Maya, D.A.; Duque Amaya, A.F.; Díaz Torres, A.G.; Acosta Maya, D.A.; Universidad EAFIT. Departamento de Ingeniería de Producción; Ingeniería, Energía, Exergía y Sostenibilidad (IEXS)A mathematical and numerical model of flow and combustion process for spark ignition engines is developed using the principles of the first and second law of thermodynamic. Availability (exergy) analysis is applied to cylinder of a spark ignition engine during the combustion process using a two-zone combustion model. Special attention is given to identification and quantification of irreversibility of combustion process and energy available basing on the isooctane fuel explosion. To predict emissions generation (greenhouse gases) a skeletal mechanism including 32 species and 61 reactions was developed and tested for different engine operations and exergy destructions.